Stone Bladed Stiletto and Slargilug Spear (spelling) look pretty fine, although personally I'd advise you to ignore the graphics and get weapons with good stats.
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Also how do u apply poision?
Old world poisons: put your poison in an empty inventory slot and right click on it. You will see your rogue kneel while he applies the poison. When you stand up, it is applied.
PoP poisons use the same right-click method, although the applying will look like casting a spell. You will see a spell casting bar while your rogues applies the poison. It will add an icon in your buff window as well.
Picklock: buy lockpicks and visit Befallen. There is a closed door to the left after zoning in. Equip your picklocks and start clicking on the door.
Newbie armor:
Check your local rogue guild manager in your starting city.
And pick a Barbarian. Or Dwarf. Or Halfling. Or Vah'Shir. Elven rogue stats are crap, I can tell you from my own experience.