If you start a new character, and have not yet created a profile for that character using the "Your Characters..." link on the site's sidebar, will that new character show up in the item collector's profile list? I guess I'm asking where does the item collector's profile list of characters come from, the site server, or a list that the item collector has assembled from snooping your eq files? Possibly, a new Allakhazam member may not have even started a profile on the site's server, so the item collector does not show any profiles available yet.
Not knowing exactly how the item collector works with the server, I can't say this for sure. It could very well send a message to the server to create a new character profile for you from scratch. I could test this out by deleting one of my profiles and then running the item collector while logging on that character, then checking if the profile came back on the server. With my newest character, I started a new profile for it manually using the site link, then ran the item collector. It did show up that way in the item collector. Only 3 of my 5 characters show up in the item collector profile list. Two characters I have not played since before I installed the item collector. They do not show up in the list for uploading. But I suspect if I do some play time with them, while running item collector, the item collector will then add them to it's list.
To sum up:
1. Maybe a character's profile already needs to exist on the server for it to show up on the item collector's profile list.
2. Also maybe a character needs to be played at least one time along with the item collector, for it to show up on the item collector's profile list.