Shadow will always be better for solo'ing. A PI/SoL build can be fairly good though, just takes *much* longer to get as good :P
First points into Spirit Tap, then towards SoL. Probably look like
this.
Then start working towards PI. Of course, you won't be able to reach it without respeccing out of Spirit Tap. I'd do this some time in your 60's.
Final spec probably something like
this. Holy Focus, Imp Mana Burn, and Martyrdom are pretty much entirely PvP stats by the time you hit 70, as getting hit much less crit in an instance pretty much means you die, and casters that you want to burn their mana usually have tens of thousands (too big to burn). If you don't intend to PvP, I'd trade those into Mental Agility/Absolution and Inspiration.