The neutral auction house used to be in Booty Bay, at least during beta. But for some reason Blizzard relocated it to Gadgetzan when they released the game. I expect that Blizzard had their reasons, but I find it rather a shame. It’s fairly easy for low level characters of both factions to reach Booty Bay. My alliance characters have swam there in their low teens and horde characters can take a ship. But Gadgetzan is a pain in the butt to get to. You almost have to be about level 40 to get there. Thus the neutral auction house is not nearly as access able now as it was during beta.
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So if you have both alliance and horde character on a server, that's one way you can exchange items back and forth.
I’m afraid that won’t work. Characters on the same account cannot bid on their own auctions. You would either have to have a second account or have the help of a friend.